How to: Change to a different printer in Word.
Solution:
Select 'Print...' from the 'File' menu. Select a printer from the 'Printers' drop-down list and set as default.
1) Select the 'File' menu and select 'Print...'.
2) Select a printer from the 'Name' drop-down list box in the 'Printer' box.
NOTE: If the desired printer is not listed, a new print driver must be installed through the Windows Control Panel.
3) Click 'OK'.
NOTE: Selecting a new printer for Word also changes the default printer for all Windows applications.